Shape-iron-base alloy

专利摘要:
An iron-based shape-memory alloy excellent in a shape-memory property and a corrosion resistance, consisting essentially of: chromium : from 0.1 to 5.0 wt.%, silicon : from 2.0 to 8.0 wt.%, manganese : from 1.0 to 14.8 wt.%, at least one element selected from the group consisting of: nickel : from 0.1 to 20.0 wt.%, cobalt : from 0.1 to 30.0 wt.%, copper : from 0.1 to 3.0 wt.%, and nitrogen : from 0.001 to 0.400 wt.%, where, Ni + 0.5 Mn + 0.4 Co + 0.06 Cu + 0.002 N >/= 0.67 (Cr + 1.2 Si), and the balance being iron and incidental impurities. o
公开号:SU1826994A3
申请号:SU894613799
申请日:1989-04-04
公开日:1993-07-07
发明作者:Moriya Yutaka；Sanpej Tetsuya；Tagava Khisatosi
申请人:Nippon Kokan Kk；
IPC主号:

专利说明:

The invention relates to the field of metallurgy, in particular to iron-based alloys with a shape memory effect.
The purpose of the invention is to increase corrosion resistance while maintaining a percentage of the restored strain of 30%.
An alloy based on iron is proposed with the effect of shape memory, consisting of wt.%: 0.5-5.0 chromium, 2.5-7.6 silicon,
1.4-14.8 manganese and at least one element selected from the group comprising 1.9-18.2 wt.% Nickel, 1.3-27.9 wt.% Cobalt, 0.5- 2.7 wt.% Copper and 0.002-0.381 wt.% Nitrogen, where Ni + 0.5 Mn + 0.4 Co + 0.06 Cu + 0.002 N ^ 0.67 (Cr + 1.2 Si), iron and random impurities.
Extensive studies have been carried out to obtain an iron based alloy of the type h _C p. Capable of restoring shape. As a result, the following was discovered:
1. Chrome performs the function of reducing the energy of austenite packing defects and improves the corrosion resistance of the alloy. In addition, chromium has another function, namely increasing the yield strength of austenite. However, when the chromium content is below 0.5 wt.%, The desired effect cannot be achieved. On the other hand, a chromium content in excess of 5.0 wt.% Is not allowed for the following reasons: since chromium is an element forming ferrite, an increased chromium content prevents the formation of austenite. Therefore, at least one is added to the alloy according to the invention for the formation of austenite
1826994 AZ element: manganese, nickel, cobalt, copper and nitrogen, which are austenite-forming elements. For increased chromium content, the austenitic forming elements must also be added in large quantities. However, the addition of austenite-forming elements in large quantities is uneconomical. For these reasons, when the chromium content exceeds 5.0 wt.%, The need for a high content of austenite-forming elements leads to economic losses. Therefore, the chromium content should be limited to 0.5-5.0 wt.%.
2. Silicon reduces the energy of austenite packing defects. Silicon also increases the yield strength of austenite. However, when the silicon content is below 2.5 wt.%, The desired effect, as indicated, cannot be achieved. On the other hand, when the silicon content is more than 7.6 wt.%, The ductility of the alloy is seriously deteriorated and the processing ability in the hot and cold state is significantly impaired. Therefore, the silicon content should be limited to a range of 2.5 to 7.6 wt.%.
3. Manganese is a strong austenite-forming element and makes the uterine phase of the alloy prior to the application of plastic deformation exclusively consisting of austenite or mainly austenite and a small amount of ε martensite. However, when the manganese content is below 1.4 wt.%, The desired effect is not achieved. On the other hand, at> 14.8 wt.% Manganese impairs corrosion resistance and a δ phase is easily formed. Therefore, the manganese content should be limited to 1.4-14.8 wt.%.
4. Nickel is an austenitic forming element. When the nickel content is below 1.9 wt.%, The desired effect cannot be achieved. On the other hand, when the nickel content is more than 18.2 wt.%, The transformation point of ε-martensite (point MS) will shift mainly to the side of the low-temperature zone and the temperature at which plastic deformation is applied to the alloy becomes very low. Therefore, the nickel content should be limited to 1.9-18.2 wt.%.
5. Cobalt represents an austenite-forming element and has the function of making the uterine phase of the alloy, before the application of plastic deformation, exclusively consisting of austenite or, mainly, austenite and a small amount of ε-martensite. In addition, cobalt does not reduce the MS point, while manganese, nickel, copper and nitrogen reduce the MS point. Therefore, cobalt is a very effective element for regulating the MS e point. The required temperature range. However, when the cobalt content is below 1.3 wt.%, The desired effect cannot be achieved. An increase in cobalt content of more than 27.9%. Therefore, the cobalt content should be limited to 1.3-27.9 wt.%.
6. Copper is an austenite-forming element and has the function of making the uterine phase of the alloy, prior to the application of plastic deformation, as exclusively consisting of austenite or, mainly, austenite and a small amount of ε martensite. In addition, copper has the function of improving the corrosion resistance of the alloy. However, as mentioned, when the alloy content is below 0.5 wt.%, The desired effect cannot be achieved. On the other hand, with a copper content exceeding 2.7 wt.%, The formation of ε-martensite is excluded. The reason is that copper has the function of increasing the energy of stacking defects of austenite. Thus, the copper content should be limited to the range of 0.5-2.7 wt.%.
7. Nitrogen is an austenite-forming element and has the function of making the uterine phase of the alloy, prior to the application of plastic deformation, exclusively consisting of austenite or, mainly, austenite and a small amount of ε martensite. In addition, nitrogen has the function of improving the corrosion resistance of the alloy and increasing the yield strength of austenite. However, when the nitrogen content is below 0.002 wt.%, The desired effect cannot be achieved. On the other hand, when the nitrogen content is more than 0.381 wt.%, The formation of chromium and silicon nitrides is simplified and the property to restore the shape of the alloy is deteriorated. Therefore, the nitrogen content should be limited to the range of 0.002-0.381 wt.%.
8. The ratio of the total content of austenite-forming elements to the total content of ferrite-forming elements:
it is necessary before applying plastic deformation that the uterine phase of the alloy at a certain temperature consist solely of austenite or mainly austenite and a small amount of ε-martensite. Therefore, according to the present invention, the following formulas should be satisfied.
J mo mentioned limitations of the chemical composition of the proposed alloy:
Ni + 0.5 Mn + 0.4 Co + 0.06 Cu + 0.002 N> ^ 0.67 (Cr + 1.2 Si)
The ability of austenite-forming elements contained in the alloy according to the invention to form austenite is expressed as follows in terms of nickel equivalent: Nickel equivalent: Ni + 0.5 Mp + 0.4 Co + 0.06 Cu + 0.002 N.
The nickel equivalent is an indicator of the ability to form austenite.
The ability of the ferrite-forming elements contained in the alloy according to the invention to form ferrite is expressed as follows in terms of the chromium equivalent: Chromium equivalent: Cr + 1.2 Si.
The chromium equivalent is an indicator of the ability to form ferrite.
If the above formula is satisfied, before applying plastic deformation to the alloy at a certain temperature, the masterbatch phase of the alloy can exclusively consist of austenite or mainly austenite and a small amount of ε-martensite.
9. The content of carbon, phosphorus and sulfur, which are impurities, should be: up to 1 wt.% Carbon, 0.1 wt.% Phosphorus and 0.1 wt.% Sulfur.
Now, the proposed iron-based alloy capable of restoring its shape will be described in detail with examples in comparison with alloy steels outside the scope of the present invention.
Example. Alloy steels having a chemical composition within the scope of the invention (Table 1) were melted in a melting furnace at atmospheric pressure or in vacuum, then cast into ingots. Then, the obtained ingots were heated to a temperature in the range of 1000-1250 ° C and hot rolled to a thickness of 12 mm for the preparation of alloy steel samples according to the invention (samples according to the invention) No. 1-12 and comparative alloy steel samples outside the scope of the present invention (samples for comparison) No. 1-9.
After that, the properties were determined to restore the shape and corrosion resistance for each sample by the following methods.
The results of these tests are presented in table. 2.
(1) Property to restore form:
The property of restoring the shape was investigated by a tensile test, which consisted of the following: a sample was cut in the form of a round bar with a diameter of 6 mm and an estimated length of 30 mm from each sample No. 1-11 according to the invention and comparative samples 1-9 prepared as described; 4% tensile strain was applied to each cut sample at the temperature indicated in the table. 2, then each sample was heated to a certain temperature above the point Af and close to the point Af, then the calculated length of each sample was measured after applying tensile force and heating: and the degree of shape recovery was calculated based on the measurement result of the estimated length to evaluate the property of the alloy to restore shape for each sample. The result of the tensile test is also shown in table. 2 in the column Property to restore the form.
The criteria for evaluating the shape retrieval properties were as follows:
©: a degree of shape recovery of at least 70%.
o: the degree of restoration of the form from 30 to below 70%; and: degree of recovery of the form below 30%.
The degree of recovery of the form was calculated according to the following formula:
The degree of recovery,% Li - L
X 100
Li - Lo where Lo is the initial calculated sample length;
Li is the estimated length of the sample after the application of tensile force:
Bg is the calculated length after heating.
Since the MS point is different for the samples, the optimum temperature for the application of plastic deformation was established for each sample. Such temperatures are indicated in Table 2 in the column Deformation temperature.
(2) Corrosion resistance.
To determine the corrosion resistance of each sample No. 1-12 according to the invention and comparative samples No. 1-9, an air test was used for a year. After completion of the test, the ratio of the total area affected by the rust of the parts to the unit area on the surface of each sample was determined (the rust occurrence coefficient will be simply referred to below), and the state of rust occurrence was estimated7 on the basis of the thus determined rust occurrence coefficient for each sample. The result of this test is also shown in table. 2 in the column Corrosion Resistance. 5
The criteria for evaluating the occurrence of rust were as follows:
o: the coefficient of occurrence of rust is less than 20% x: the coefficient of occurrence of rust is 1 θ equal to at least 20%.
As described in detail, an iron-based alloy capable of restoring shape, according to the invention, has the property of restoring shape and corrosion resistance and can be used to connect pipes, various fasteners, etc., as well as biomat, rial, moreover it allows to reduce jq production costs and therefore to obtain positive effects for industrial applications.

权利要求:
Claims (1)
[1]
Claim
An iron-based alloy with a shape-memory effect of 25 containing manganese, silicon and chromium, characterized in that, in order to increase the corrosion resistance while maintaining a percentage of the restored strain of at least 30%, the alloy additionally contains at least one component from the group including nickel, cobalt, copper and nitrogen, in the following ratio of components, wt.%:
Chromium 0.5-5 Silicon 2.5-7.6 Manganese 1.4-14% at least, one component from the group nickel 1.9-18 ,; Cobalt 1.3-27% Copper 0.5-2.7 Nitrogen 0.002-0.3!
subject to the relation
Ni + 0.5 MP + 0.4 Co + 0.06 Cu + 0.02 N>
> 0.67 (Cr + 1.2 Si)
Iron Else
Table 1
Alloy Chemical composition (Wt,%) SG Si Mp Ni With Si N Proposed 3.8 2,5 14.3 6.0 - - 0.003 3,5 5.8 12.1 7.5 - - 0.003 3.6 7.6 10.5 10.3 -. - 0.004 4.8 5.9 1.4 7.5 14.3 - - 0.5 6.2 12,4  8.1 6.7 - 0.003 4,5 5.9 14.6 1.9 1.3 1.8 . 0.013 3.8 5.8 5.8 18.2  - - - 4.7 6.3 8.8 - 27.9 - 0.003 1,0 5.9 12.3 7.0 - 0.5 0.002 1,2 6.1 7.8 6.5 6.8 2.7 0.004 3,1 6.3 10.7 7.5 - - 0.381 5,0 5.8 14.8 4.9 - - 0.002 Prototype 3.4 5.9 16.6 5.8 -0.004
Table 2
No. No. p / p t strain Ezf Corrosion resistance Proposed alloy Com of ra ABOUT ABOUT _n_ Room temperature © ABOUT - 80 ° C © ABOUT Room temperature © ABOUT Room temperature ABOUT ABOUT Room temperature © ABOUT - 196 ° C Ό 0 Room temperature © 0 Com of ra-80 ° C © ABOUT ABOUT ABOUT - 80 ° C © ABOUT Com of ra © ABOUT Prototype Room temperature X ABOUT

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法律状态:

优先权:

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申请号 | 申请日 | 专利标题

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JP8349588|1988-04-05|

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